A. Lecomte et al., Dynamical scaling property of colloidal aggregation in a zirconia-based precursor sol during gelation, J APPL CRYS, 33(1), 2000, pp. 496-499
Zirconia precursor gels, prepared in the zirconium n-propoxide, n-propanol,
acetylacetone and water system, are studied by small angle X-ray scatterin
g (SAXS). The SAXS intensity pattern exhibits a pronounced maximum for a sc
attering vector q different from zero. The intensity maximum of the finite
q-vector peak increases during gelation while its position qm moves towards
smaller and smaller q-vectors. The SAXS intensity distribution is well acc
ounted for by recent direct numerical calculations of diffusion-limited clu
ster aggregation (DLCA). The structural aspects of cluster growth can be de
scribed by scaling assumptions. The position q(m) of the intensity maximum
and the structure function S(q/q(m),t) are shown to scale according to S(q/
q(m),t) = q(m) (t)(-d) F(q/q(m)) where F(q/q(m)) is a time-independent scal
ing function. This scaling requires d= D-f, the fractal dimension of the cl
usters, instead of d= 3 for spinodal decomposition. The gel structure is ma
de up of connected fractal clusters, around 50 nm in size, with an apparent
fractal dimension of 1.7, resulting from the aggregation of very small pri
mary particles about 2.5 nm in diameter.