The mechanism for the persistent photoconductivity of oxygen deficient
YBa2Cu3O6+x films is proposed. Photoexcited electrons fill vacant ele
ctron orbitals of O- in the Cu-O-... chains. Photoexcited holes remain
free and cause an increase in the density of mobile holes in CuO2 pla
nes. To recombine with holes the electrons have to overcome an barrier
of approximately 1 eV, corresponding the excitation energy from the l
ocalized levels in the chains into the upper conduction band. Proposed
model of a photoinduced charge transfer is consistent with available
experimental data.