A study on the beta-elimination reaction from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl bromide induced by amines in dimethylsulfoxide with formation of p-nitrostyrene
S. Alunni et A. Rocchi, A study on the beta-elimination reaction from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl bromide induced by amines in dimethylsulfoxide with formation of p-nitrostyrene, J CHEM R-S, (2), 2000, pp. 62-63
Second order rate constants k(E) M-1 s(-1) for the beta-elimination reactio
n from N-[2-(p-nitrophenyl)ethyl]quinuclidinium and 2-(p-nitrophenyl)ethyl
bromide induced by amines of different structure in dimethylsulfoxide at 50
degrees C have been measured. Application of the Bronsted equation shows a
similar behaviour of the two substrates, with values of beta = 0.649 and 0
.584 respectively.