A dense grid of reference iodine lines for optical frequency calibration in the range 595-655 nm

A dense grid of reference lines in the hyperfine structure of the B-X trans itions of molecular iodine (I-127(2)) is presented. Frequencies of 481 "t"- hyperfine components in 15 vibrational bands covering the wavelength range 595-655 nm were determined with an absolute accuracy of 1.0 MHz (1 sigma un certainty). Spectra were obtained by Doppler-free saturation spectroscopy u sing a cw ring-dye laser of 1-MHz bandwidth. Center-of-gravity frequencies of rovibronic lines, determined by correcting for the calculated hyperfine shift, are included separately in a least-squares parametrization for each band. From the obtained molecular constants a prediction is made for all t- hyperfine components of the 15 bands covering 595-655 nm. Hence a dense gri d of reference lines of 1 MHz (1 sigma) absolute accuracy is created, with a Line in each interval of 1 cm(-1) in the entire range. This spectral atla s of about 3400 lines may provide a useful calibration tool in many laborat ories. (C) 2000 Academic Press.