Rotational wavepacket dynamics of the C-60 molecule

Authors
Citation
I. Jex et G. Alber, Rotational wavepacket dynamics of the C-60 molecule, J PHYS B, 33(8), 2000, pp. 1663-1674
Citations number
11
Categorie Soggetti
Physics
Journal title
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
ISSN journal
09534075 → ACNP
Volume
33
Issue
8
Year of publication
2000
Pages
1663 - 1674
Database
ISI
SICI code
0953-4075(20000428)33:8<1663:RWDOTC>2.0.ZU;2-H
Abstract
The wavepacket dynamics of (non-stationary) rotational quantum states of th e C-60 molecule are investigated. It is demonstrated that the icosahedral s ymmetry of this molecule gives rise to a variety of peculiar coherence phen omena which are characteristic for this specific discrete symmetry group. O n the one hand, the dynamics of these wavepackets reflects the underlying c lassical dynamics on the associated manifold of group space. On the other h and, these dynamics also exhibit characteristic quantum features such as th e appearance of fractional revivals, of quantum tunnelling between differen t classically accessible regions of the associated manifold of group space and of cat-like quantum states which are generated in the course of the tim e evolution.