An experimental methodology was developed for identification of mechanical
behavior laws, in which the evolution of the stresses and strains in the su
rface of the samples is determined by X-ray diffraction and electric resist
ance strain gages, respectively, as a function of the loading in four-point
bending tests. The determined stress-strain curve is then characteristic o
f the near-surface layers of the samples. The method was validated for diff
erent steels by comparing the results of samples with homogeneous propertie
s on the cross section with the results of tension tests. The developed met
hodology was applied to the study of steel samples submitted to surface tre
atments, presenting gradients of chemical composition, microstructure, and
mechanical properties from the surface to the bulk material.