Investigation of neodymium complex with acid chrome blue K by beta-correction spectrophotometry

Citation
Hw. Gao et al., Investigation of neodymium complex with acid chrome blue K by beta-correction spectrophotometry, J INDIAN CH, 77(4), 2000, pp. 192-193
Citations number
3
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF THE INDIAN CHEMICAL SOCIETY
ISSN journal
00194522 → ACNP
Volume
77
Issue
4
Year of publication
2000
Pages
192 - 193
Database
ISI
SICI code
0019-4522(200004)77:4<192:IONCWA>2.0.ZU;2-L
Abstract
The neodymium complex with acid chrome blue K (ACBK) at pH 10 has been stud ied in detail by beta-correction spectrophotometry. The cationic surfactant , cetyltrimethylammonium bromide (CTAB) is useful for increasing the sensit ivity and solubility of ligand and:complex. The characteristic factors of c omplex are calculated, for example, complex ratio and stability constant. R esults show that Nd(ACBK)(3) is formed and its real not apparent molar abso rptivity is the first to be determined as follows : epsilon 520/Nd(ACBK)(3) = 5.54 x 10(4) dm(3) mol-' cm(-1) at pH 10. In addition, the cumulative st ability constant of complex Nd(ACBK)(3) is still computed to be 1.72 x 10(1 6) in ionic strength 0.1 M and at temperature 15 degrees.