Heat capacity measurements of Haldane-gap antiferromagnetic NENP are p
erformed. An anomalous broad peak was observed below 1K besides Schott
ky anomaly corresponding to Haldane-gap. This broad peak exists under
zero magnetic field and disappears under external magnetic field of 3T
. We have also measured the heat capacities of both Cu-doped and Zn-do
ped samples, because impurity and end-chain spins may be responsible f
or the observed anomaly as well as the possibility of long range order
.