M. Endo et al., Miscibility and crystallization of polytetrafluoroethylene/poly(tetrafluoroethylene-co-perfluoropropylvinyl ether) blends, MACRO RAPID, 21(7), 2000, pp. 396-400
Miscibility and crystallization behavior have been studied for polytetraflu
oroethylene(PTFE)/ poly(tetrafluoroethylene-co-2 mol-% perfluoropropylvinyl
ether)(PFA copolymer) blends by the use of differential scanning calorimet
ry, electron microscopy, X-ray diffractometry and dynamic mechanical spectr
oscopy. In the amorphous phase, the two components were miscible with each
other over all blending ratios, and it was found that the PFA copolymer was
compatible with the PTFE matrix. when the PFA content is less than or equa
l to 50 wt.-%, while PTFE was mixed in the PFA matrix when the PFA content
is >50 wt.-%. All the blends were crystalline as well as PTFE and PFA. The
crystallization behavior was closely connected to the polymer composition o
f the amorphous state described above. It was conjectured that the crystall
ization is controlled by the PTFE matrix when the PFA content is less than
or equal to 50 wt.-%, while by the PFA matrix when the PFA content is >50 w
t.-%.