We present time-resolved spectrophotometry of the pulsating DA white dwarf
G29-38. As in previous broad-band photometry, the light curve shows the pre
sence of a large number of periodicities. Many of these are combination fre
quencies, i.e. periodicities occurring at frequencies that are sums or diff
erences of frequencies of stronger, real modes. We identify at least six re
al modes, and at least five combination frequencies. We measure line-of-sig
ht velocities for our spectra and detect periodic variations at the frequen
cies of five of the six real modes, with amplitudes of up to 5 km s(-1). We
argue that these variations reflect the horizontal surface motion associat
ed with the g-mode pulsations. No velocity signals are detected at any of t
he combination frequencies, confirming that the flux variations at these fr
equencies do not reflect physical pulsation, but rather reflect mixing of f
requencies owing to a non-linear transformation in the outer layers of the
star. We discuss the amplitude ratios and phase differences found for the v
elocity and light variations, as well as those found for the real modes and
their combination frequencies, both in a model-independent way and in the
context of models based on the convective-driving mechanism. In a companion
paper, we use the wavelength dependence of the amplitudes of the modes to
infer their spherical degree.