A rotaxane of a 1,1 '-disubstituted ferrocene and beta-cyclodextrin

Authors
Skinner, PJ Blair, S Kataky, R Parker, D
Citation
Pj. Skinner et al., A rotaxane of a 1,1 '-disubstituted ferrocene and beta-cyclodextrin, NEW J CHEM, 24(5), 2000, pp. 265-268
Citations number
17
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
24
Issue
5
Year of publication
2000
Pages
265 - 268
Database
ISI
SICI code
1144-0546(200005)24:5<265:AROA1'>2.0.ZU;2-4
Abstract
The synthesis is reported of the first rotaxane involving a bound ferroceny l moiety and beta-cyclodextrin; cyclodextrin groups are used as stoppers; i ntermediate 1:1 adduct formation in d(8)-THF was monitored by HR-DOSY metho ds (K-d = 25 mM, 293 K) and the product rotaxane, isolated in 11% yield, ha s been characterised by MMR, CD and MALDI-TOF MS.