Photoluminescence experiments in high magnetic fields reveal diamagnetic sh
ifts consistent with a type-II conduction band offset of about 55 meV for S
i/Sio(0.76)Ge(0.24). We point out that for such a type-II offset a magnetic
field induced changeover from Delta(2)- to Delta(4)-like recombination is
expected for an 8.5 nm wide quantum well, and that: this changeover can exp
lain our measurements on this well at low excitation power. The magnetolumi
nescence data provide evidence for localized and free exciton recombination
s, which are hardly separable without the magnetic field. For interpretatio
n of the data we employ calculations within an effective-mass model, obtain
ing two-particle ground-state wave functions for excitons in quantum wells
at high magnetic fields.