We explicitly check quark-hadron duality to order (m(b) - m(c))Lambda/m(b)(
2), for b --> clv decays in the limit m(b) - m(c) much less than m(b) inclu
ding ground state and orbitally excited hadrons. Duality occurs thanks to a
new sum rule which expresses the subleading HQET form factor xi(3) or, in
other notations, a(+)((1)) in terms of the infinite mass limit form factors
and some level splittings. We also demonstrate the sum rule, which is not
restricted to the condition m(b) - m(c) much less than m(b), applying OPE t
o the longitudinal axial component of the hadronic tensor without neglectin
g the 1/m(b) subleading contributions to the form factors. We argue that th
is method should produce a new class of sum rules, depending on the current
, beyond Bjorken, Voloshin and the known tower of higher moments. Applying
OPE to the vector currents we find another derivation of the Voloshin sum r
ule. From independent results on xi(3) we derive a sum rule which involves
only the tau(1/2)((n)) and tau(3/2)((n)) form factors and the corresponding
level splittings. The latter strongly supports a theoretical evidence that
the B semileptonic decay into narrow orbitally-excited resonances dominate
s over the decay into the broad ones, in apparent contradiction with some r
ecent experiments. We discuss this issue. (C) 2000 Elsevier Science B.V. Al
l rights reserved.