Effect of ionic strength and organic solvents on the hydrogen wave in the nickel-thioglycollic acid system

Authors
Calusaru, A Olaru, M Marcu, M
Citation
A. Calusaru et al., Effect of ionic strength and organic solvents on the hydrogen wave in the nickel-thioglycollic acid system, REV RO CHIM, 44(7), 1999, pp. 651-654
Citations number
4
Categorie Soggetti
Chemistry
Journal title
REVUE ROUMAINE DE CHIMIE
ISSN journal
00353930 → ACNP
Volume
44
Issue
7
Year of publication
1999
Pages
651 - 654
Database
ISI
SICI code
0035-3930(199907)44:7<651:EOISAO>2.0.ZU;2-R
Abstract
The hydrogen catalytic discharge produced by a series of compounds in the p resence of Co2+ and Ni2+ ions is an important process that occurs in this c lass of reaction. In the nickel-thioglycollic acid system it has been found that the [Ni(C2H3O2S)(2)(NH3)(H2O)](o) complex is formed. This complex pro duces catalytic waves and behaves similarly to Co-mercaptobenzothiazole and Ni-mercaptobenzothiazole system.