Spectroscopy (IR, luminescence) and polymeric transformations of the heteroligand Eu(III) and Tb(III) complexes with unsaturated acids

Authors
Petrochenkova, NV Petukhova, MV Mirochnik, AG Karasev, VE
Citation
Nv. Petrochenkova et al., Spectroscopy (IR, luminescence) and polymeric transformations of the heteroligand Eu(III) and Tb(III) complexes with unsaturated acids, RUSS J C CH, 26(5), 2000, pp. 373-376
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
5
Year of publication
2000
Pages
373 - 376
Database
ISI
SICI code
1070-3284(200005)26:5<373:S(LAPT>2.0.ZU;2-S
Abstract
The heteroligand Eu(III) and Tb(III) complexes with acetylacetone (HAcac) a nd unsaturated acids, Ln(Acac)(2)Q . H2O, where Q is acrylic (HAcr) or meth acrylic acid, were synthesized. Radical copolymerization was carried out fo r the heteroligand Eu(Acac)(2)Acr . H2O complex and acrylic acid or methyl methacrylate and for the Tb(Acr)(3). 3H(2)O complex and acrylic acid. The c ompounds are characterized by elemental analysis, luminescence, and IR spec troscopy. The luminescence intensities of the macromolecular Eu(III) comple xes containing acetylacetonate ion are comparable with those of the monomer ic complex.