Water accelerated Sm/TMSCl reductive system: Debromination of vic-dibromides and reduction of sodium alkyl thiosulfates

Authors
Xu, XL Lu, P Zhang, YM
Citation
Xl. Xu et al., Water accelerated Sm/TMSCl reductive system: Debromination of vic-dibromides and reduction of sodium alkyl thiosulfates, SYN COMMUN, 30(11), 2000, pp. 1917-1925
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
11
Year of publication
2000
Pages
1917 - 1925
Database
ISI
SICI code
0039-7911(2000)30:11<1917:WASRSD>2.0.ZU;2-K
Abstract
a simple and efficient method for the debromination of vic-dibromides to (E )-alkenes and reduction of sodium alkyl thiosulfates to disulfides promoted by Sm/TMSCl/H2O (trace) has been described.