Novel electro-oxidizable chiral N-substituted dicarbazoles and resulting electroactive films for covalent attachment of proteins

Authors
Perie, K Marks, R Szumerits, S Cosnier, S Lellouche, JP
Citation
K. Perie et al., Novel electro-oxidizable chiral N-substituted dicarbazoles and resulting electroactive films for covalent attachment of proteins, TETRAHEDR L, 41(19), 2000, pp. 3725-3729
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
19
Year of publication
2000
Pages
3725 - 3729
Database
ISI
SICI code
0040-4039(20000506)41:19<3725:NECNDA>2.0.ZU;2-X
Abstract
Novel chiral electro-oxidizable dicarbazoles functionalized by N-succinimid yl/phthalimidyl or pentafluorophenyl carboxylates 6a-c were synthesized fro m L-lysine methyl ester 1 and characterized electrochemically. The correspo nding chiral polycarbazole films 8a-c constitute polymers suitable for cova lent grafting of proteins, as demonstrated for bovine serum albumin as a mo del compound. (C) 2000 Elsevier Science Ltd. All rights reserved.