Fractal analysis of macromolecules

Citation
Vi. Novikov et Gv. Kozlov, Fractal analysis of macromolecules, USP KH, 69(4), 2000, pp. 378-399
Citations number
141
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
69
Issue
4
Year of publication
2000
Pages
378 - 399
Database
ISI
SICI code
0042-1308(2000)69:4<378:FAOM>2.0.ZU;2-Q
Abstract
The results of studies of the fractal forms of macromolecules, whose existe nce is predetermined by the thermodynamic nonequlibrium and the presence of deterministic order, are considered. The limitations of the applicability of the polymer fractal (macromolecular coil) concept are noted. The Vilgis theory and the possibility of modelling in terms of the percolation theory and diffusion-limited irreversible aggregation are discussed. It is noted t hat not only macromolecular coils but also the sections of macromolecules b etween the topological fixing units (cross-links, entanglements) are stocha stic fractals; this is confirmed by the model of structure formation in a n etwork polymer.