NMR study on conformation of 2-benzoyl-1-methyl-3-phenylpiperidine

Authors
Szczecinski, P Gryff-Keller, A
Citation
P. Szczecinski et A. Gryff-keller, NMR study on conformation of 2-benzoyl-1-methyl-3-phenylpiperidine, B POL CHEM, 48(1), 2000, pp. 13-18
Citations number
4
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY
ISSN journal
02397285 → ACNP
Volume
48
Issue
1
Year of publication
2000
Pages
13 - 18
Database
ISI
SICI code
0239-7285(2000)48:1<13:NSOCO2>2.0.ZU;2-Q
Abstract
Temperature H-1 NMR spectra of the title compound were measured and interpr eted in terms of slow rotation about the bond between piperidine ring and b enzoyl substituent, Barrier to this rotation was calculated to be E-a = 59 kJ/mol and log(A) = -14.2.