Ay. Huc et al., Pyrobitumen occurrence and formation in a Cambro-Ordovician sandstone reservoir, Fahud Salt Basin, North Oman, CHEM GEOL, 168(1-2), 2000, pp. 99-112
The Cambro-Ordovician Barik Sandstone reservoirs in the Fahud Salt Basin in
Oman contain bitumen which may fill up to 40% of the porosity. In well Jal
eel-1, this bitumen was isolated (according to kerogen procedure) and typed
by NMR, elemental analysis and density measurements. The isolated bitumen
is characterized by: (1) a highly aromatic character (NMR 75% C-Aro, H/C at
omic ratio: 0.65), (2) a very high sulphur content (4.2%) and (3) a relativ
ely high density (1.3-1.4 g/cm(3)). The insolubility and the reflectivity o
f the bitumen (1.2% Vr) qualify it as a low mature pyrobitumen. The combina
tion of Rock-Eval and density data was used to calculate the actual volume
of the pyrobitumen in the rock, as a percentage of porosity. It was found t
hat the pyrobitumen volume shows a negative correlation with total porosity
, indicating that small pores are more invaded by bitumen than larger ones.
Finally, closed system pyrolysis experiments, performed on oils with diffe
rent NSO contents, indicate that an in situ oil with a very high content of
NSO compounds is required to generate such large amounts of pyrobitumen in
the pore system. These observations suggest that the precursor oil of the
current pyrobitumen was a very heavy oil tentatively assumed to be the resu
lt of a severe biodegradation. Basin modeling shows that the reservoir was
charged already in Devonian times. A major uplift brought the oil accumulat
ion near the surface during the Carboniferous and a rather regular burial t
o the present day position (4500 m, 140 degrees C) (Loosveld et al., 1996).
This scenario, involving a residence time at shallow depth, strengthens th
e biodegradation hypothesis. The numerical modeling, which involves the IFP
kinetic model for secondary oil cracking, suggests that pyrobitumen format
ion is a very recent event. Inclusion of pyrobitumen particles within quart
z overgrowth, containing fluid inclusions, provides an upper temperature li
mit for the beginning of pyrobitumen formation which comforts the result of
kinetic modelling. (C) 2000 Elsevier Science B.V. All rights reserved.