The results of ab initio molecular dynamics simulations of the solvation of
Al3+ and its hydrolyzation products in water clusters are reported. Al3+ i
ons in water clusters (6 less than or equal to n less than or equal to 16)
form a stable hexa-hydrate Al(H2O)(6)(3+) complex in finite temperature sim
ulations. The deprotonated Al(H2O)(2)(OH)(4)(-) complex evolves into a tetr
a-coordinated Al(OH)(4)(-) aluminate ion with two water molecules in the se
cond cluster solvation shell. The influence of a strong polarization of the
OH bonds in the first solvation shell on the proton transfer mechanism is
discussed. (C) 2000 Elsevier Science B.V. All rights reserved.