Hydrophilic-hydrophobic balance of bis(octylethylenediamine) Zn(II), Cd(II), and Pd(II) chlorides in methanol/water and chloroform/water systems

Authors
Iida, M Er, H Hisamatsu, N Tanase, T
Citation
M. Iida et al., Hydrophilic-hydrophobic balance of bis(octylethylenediamine) Zn(II), Cd(II), and Pd(II) chlorides in methanol/water and chloroform/water systems, CHEM LETT, (5), 2000, pp. 518-519
Citations number
7
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
5
Year of publication
2000
Pages
518 - 519
Database
ISI
SICI code
0366-7022(20000505):5<518:HBOBZC>2.0.ZU;2-V
Abstract
Double-chained bis(N-octylethylenediamine ( = OE)) complexes, such as Zn(OE )(2)Cl-2, Cd(OE)(2)Cl-2 and Pd(OE)(2)Cl-2, were prepared and their selectiv e solubilities in water/chloroform and water/methanol solutions were studie d. Although all the complexes are poorly soluble in water, they showed clea rly different solubilities in the water/organic mixed solvents depending on each amphiphilic character.