Two types of periodic surfaces were fabricated by utilizing two-dimensional
ly ordered arrays, in one case as a template and in another as a mask. In t
he first case, a bulb-like microstructured surface was formed, and, in the
second, a cylinder-like microstructure. The Raman spectra of these films in
dicate that they consist mostly of diamond and therefore have a high refrac
tive index as well as other well-known properties of diamond, making them a
ttractive for photonic, electronic, and electrochemical applications.