As the boron incorporation level and the wavelength of the exciting laser w
ere varied, we observed systematic modifications of the Raman spectra of ho
moepitaxial diamond films. A pronounced change in the lineshape of the zone
-center optical Raman peak as well as a wide and structured signal at lower
wavenumbers appeared simultaneously when the boron incorporation was incre
ased above an abrupt threshold around 3 x 10(20) cm(-1). This threshold was
found to depend on the excitation laser wavelength. Possible origins for t
he wide peaks at 500 and 1225 cm(-1) are also discussed. (C) 2000 Elsevier
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