Na. Fox et al., Properties of electron field emitters prepared by selected area depositionof CVD diamond carbon films, DIAM RELAT, 9(3-6), 2000, pp. 1263-1269
Selected area depositions (SAD) of diamond films were successfully achieved
on silicon by two different approaches. In the first case, a standard lift
-off technique employing a patterned SiO2 layer was used as a mask, and in
the second case commercial ink-jet printer technology was adapted to be use
d to seed diamond nano-grit onto silicon. Patterned, boron-doped diamond pa
ds roughly 5.6 mu m in diameter were formed by CVD growth on patterned SiO2
/Si substrates and found to be composed of closely packed carbon clusters a
pproximately 250-800 nm in size each containing 50-nm particles embedded in
them. The patterned diamond film seeded by ink-jet printing formed after C
VD growth with in situ boron-doping, dots (85 mu m in diameter) containing
poly-crystals in the nanometre range. The resulting patterned diamond films
were characterised by Raman and scanning electron microscope (SEM) analysi
s and then configured as cold cathode field emitters to determine their ele
ctron emission performance. The results suggest that patterned diamond film
s produced by ink-jet printing offer a simpler method for fabricating plana
r diamond emitter arrays with field emission and conduction properties whic
h could be tailored to improve the performance and fabrication cost of cold
held emitters in state-of-the-art field emission displays. (C) 2000 Elsevi
er Science S.A, All rights reserved.