Novel (methyl)- and (acetyl)palladium complexes containing bis(pyrazolyl)borate ligands - Dynamic equilibrium between eta(2) and eta(1) forms for thecomplex Bp*(Me)(PCy3)Pd [Bp* = dihydridobis(3,5-dimethylpyrazolyl)borate]

Authors
Diaz-Requejo, MM Nicasio, MC Belderrain, TR Perez, PJ Puerta, MC Valerga, P
Citation
Mm. Diaz-requejo et al., Novel (methyl)- and (acetyl)palladium complexes containing bis(pyrazolyl)borate ligands - Dynamic equilibrium between eta(2) and eta(1) forms for thecomplex Bp*(Me)(PCy3)Pd [Bp* = dihydridobis(3,5-dimethylpyrazolyl)borate], EUR J INORG, (6), 2000, pp. 1359-1364
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
6
Year of publication
2000
Pages
1359 - 1364
Database
ISI
SICI code
1434-1948(200006):6<1359:N(A(CC>2.0.ZU;2-0
Abstract
A series of (methyl)palladium complexes of general formula Bp'Pd(CH3)(L) [B p' = Bp = dihydridobis(pyrazolyl)borate; Bp' = Bp* = dihydridobis(3,5-dimet hylpyrazolyl)borate, L = phosphane] has been synthesised. The interaction o f these alkyl complexes with carbon monoxide produces the acetyl derivative s Bp'Pd(C(O)Me)(L), one of the members of this series, BpPd[C(O)Me](PPh3), being structurally characterised by X-ray diffraction studies.