Copolymers of phenacyl methacrylate with glycidyl methacrylate: synthesis,characterization and monomer reactivity ratios

Authors
Soykan, C Ahmedzade, M Coskun, M
Citation
C. Soykan et al., Copolymers of phenacyl methacrylate with glycidyl methacrylate: synthesis,characterization and monomer reactivity ratios, EUR POLYM J, 36(8), 2000, pp. 1667-1675
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN POLYMER JOURNAL
ISSN journal
00143057 → ACNP
Volume
36
Issue
8
Year of publication
2000
Pages
1667 - 1675
Database
ISI
SICI code
0014-3057(200008)36:8<1667:COPMWG>2.0.ZU;2-C
Abstract
Copolymers with various proportions of phenacyl methacrylate (PAMA) and gly cidyl methacrylate (GMA) were prepared by free radical-polymerization in so lution in 1,4-dioxane using 2,2'-azobisisobutyronitrile as initiator at 70 degrees C. The polymers were characterized by infrared and H-1 and C-13 nuc lear magnetic resonance (NMR) spectroscopy. The copolymer compositions were determined by H-1-NMR spectra. The reactivity ratios were calculated by bo th Fineman-Ross and Kelen-Tudos methods. Glass transition and decomposition temperatures of copolymers were determined. (C) 2000 Elsevier Science Ltd. All rights reserved.