Hj. Mattausch et al., Electrical/thermal properties of nonplanar polyoxides and the consequent effects for EEPROM cell operation, IEEE DEVICE, 47(6), 2000, pp. 1251-1257
The electrical/thermal properties of nonplanar polyoxides and the resulting
effects for EEPROM operational margins are reported. The polyoxide between
floating gate (FG) and control gate (CG) of FLOTOX-type EEPROM cells is no
nplanar because it always contains edges, where CG wraps over PG, At such e
dges a highly stable electrical passivation of Fowler-Nordheim (FN) leakage
currents occurs, which can cause a degradation of EEPROM operational margi
ns, due to an electron discharge mechanism from the FG of charged EEPROM ce
lls during the first charging operation after conventional baking. The EEPR
OM cell study includes the dependence on repeated passivation/depassivation
of the polyoxide, on baking temperature and baking time. It is found that
the average magnitude of the electron discharge is reduced after each passi
vation/depassivation cycle, which points to a progressive increase of the n
umber of electrons captured in deep neutral electron traps at the polyoxide
edges. Analysis of the temperature dependence Leads to an activation energ
y (thermal detrapping energy of the electrons) of 1.3 eV for the degradatio
n mechanism of EEPROM cell operational margins as well as the nonplanar pol
yoxide depassivation.