Synthesis, characterization, crystal structures, and reactions of trigonalbipyramidal tin(IV) complexes containing a tetradentate tripodal tristhiolatophosphine ligand. Use in the one-step synthesis of an iron(IV) complex

Authors
Clark, KA George, TA Brett, TJ Ross, CR Shoemaker, RK
Citation
Ka. Clark et al., Synthesis, characterization, crystal structures, and reactions of trigonalbipyramidal tin(IV) complexes containing a tetradentate tripodal tristhiolatophosphine ligand. Use in the one-step synthesis of an iron(IV) complex, INORG CHEM, 39(11), 2000, pp. 2252
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
11
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000529)39:11<2252:SCCSAR>2.0.ZU;2-E
Abstract
Reactions of PhSnCl3 with the lithium salts of the tristhiolates, [P(C6H4-2 -S)(3)](3-), (PS3)(3-), [P(C6H3-5-Me-2-S)(3)](3-), (P'S-3)(3-) and [P(C6H3- 3-Me3Si-2-S)(3)](3-), (P " S-3)(3-), in thf at 0 degrees C, afford the corr esponding distorted, trigonal bipyramidal complexes PhSn(PS3) (1), PhSn(P'S -3) (2), and PhSn(P " S-3) (3). The crystal structure of each complex was o btained. Addition of solid FeCl3 (2 equiv) to a CH2Cl2 solution of 3 caused the immediate formation of the purple iron(IV) complex [FeCl(P " S-3)].