O. Baehr et al., PREPARATION OF BORON-NITRIDE THIN-FILMS BY MICROWAVE PLASMA-ENHANCED CVD, FOR SEMICONDUCTOR APPLICATIONS, Materials science & engineering. B, Solid-state materials for advanced technology, 46(1-3), 1997, pp. 101-104
Thin films of boron nitride (BN) have been deposited on silicon and in
dium phosphide (InP) substrates at low temperature (approximate to 300
degrees C) using a microwave plasma CVD system. The source material i
s molten borane-dimethylamine. The vapour was decomposed in a microwav
e nitrogen and argon plasma. The index of refraction and the thickness
of the films have been determined by ellipsometry. FTIR spectroscopy
was used for a fast phase identification. The composition was analyzed
by X-ray photoelectron spectroscopy (XPS). The electrical properties
of the films were evaluated by capacitance-voltage (C-V) measurements
of metal/BN/semiconductor (MIS) structures. From these results a minim
um interface state density of 3.5 10(11) cm(-2) eV(-1) and a dielectri
c constant of 5.2 have been deduced. (C) 1997 Elsevier Science S.A.