Ferroelectric electron emission has two possible sources: rapid polarizatio
n switching and surface plasma discharge. The present paper uses an X-ray d
iffraction (XRD) method to support the theory of rapid polarization switchi
ng for lead zirconate titanate samples. A decrease in the 002 peak value an
d an increase In the 200 peak value were observed after electron emission i
n two types of samples, which were doped with lanthanum and neodymium, A co
mparison of the XRD data for the samples showed that a high-density electro
n emission was related to a high-value polarization switch. These results w
ere consistent with the theory of rapid polarization switching.