Hydroformylation reactions in supercritical carbon dioxide using insolublemetal complexes

Authors
Sellin, MF Cole-Hamilton, DJ
Citation
Mf. Sellin et Dj. Cole-hamilton, Hydroformylation reactions in supercritical carbon dioxide using insolublemetal complexes, J CHEM S DA, 11, 2000, pp. 1681-1683
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Volume
11
Year of publication
2000
Pages
1681 - 1683
Database
ISI
SICI code
0300-9246(2000)11:<1681:HRISCD>2.0.ZU;2-C
Abstract
P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can sho w high activity and selectivity in the hydroformylation of hex-1-ene; remov ing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amoun ts of rhodium and the catalyst can be reused several times.