Crystal structure and magnetic behaviour of a two-dimensional complex [Cu(dmen)](2)[Fe(CN)(6)] (dmen=2-dimethylaminoethylamine) with an exceptional cyano-bridging

The cyanide bridged bimetallic assembly [Cu(dmen)](2)[Fe(CN)(6)] (dmen=2-di methylaminoethylamine) has been prepared and characterized by elemental ana lyses, infrared and electronic spectroscopy. The crystal structure of the c ompound consists of a two-dimensional polymeric sheet with two different ri ngs, one a four membered square ring and another a twelve membered hexagona l ring. Each iron(II) ion has two free, two nearly linear bridging and two end-on bridging cyanide groups. In the crystal all the copper(II) ions have a distorted square based pyramidal geometry. From magnetic susceptibility measurements, the complex was found to exhibit a weak ferromagnetic interac tion between the nearest copper atoms.