The synthesis of novel trisphosphoranylphosphine and its oxide

Citation
Wh. Wang et al., The synthesis of novel trisphosphoranylphosphine and its oxide, J CHEM S P1, 11, 2000, pp. 1673-1675
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X → ACNP
Volume
11
Year of publication
2000
Pages
1673 - 1675
Database
ISI
SICI code
0300-922X(2000)11:<1673:TSONTA>2.0.ZU;2-F
Abstract
A new trisphosphoranylphosphine oxide 1 bearing three sigma(5)lambda(5)P-si gma(4)lambda(5)P bonds was synthesized through an efficient method in which N,N-dialkylphenylacetamide played an important role. Chloroform reduced th e phosphine oxide 1 to the corresponding phosphine 2. The crystal structure of 2 was determined.