Nickel catalyzed cascade conversion of propargyl halide and propargyl alcohol into 4,6-dimethyl-5-cyano-2-pyrone in water

Authors
Rosas, N Salmon, M Sharma, P Alvarez, C Ramirez, R Garcia, JL Arzoumanian, H
Citation
N. Rosas et al., Nickel catalyzed cascade conversion of propargyl halide and propargyl alcohol into 4,6-dimethyl-5-cyano-2-pyrone in water, J CHEM S P1, 10, 2000, pp. 1493-1494
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X → ACNP
Volume
10
Year of publication
2000
Pages
1493 - 1494
Database
ISI
SICI code
0300-922X(2000)10:<1493:NCCCOP>2.0.ZU;2-Y
Abstract
Reaction of propargyl halide or alcohol with CO and KCN in the presence of Ni(CN)(2) in a basic aqueous medium affords 4,6-dimethyl-5-cyano-2-pyrone.