The synthesis of vicinal halohydrin phosphates via highly regioselective ring opening of epoxides with dialkyl halophosphate

Authors
Ding, YX Hu, J
Citation
Yx. Ding et J. Hu, The synthesis of vicinal halohydrin phosphates via highly regioselective ring opening of epoxides with dialkyl halophosphate, J CHEM S P1, 10, 2000, pp. 1651-1655
Citations number
17
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X → ACNP
Volume
10
Year of publication
2000
Pages
1651 - 1655
Database
ISI
SICI code
0300-922X(2000)10:<1651:TSOVHP>2.0.ZU;2-4
Abstract
Various titanium(IV) reagents catalyze the ring opening of epoxides by dial kyl halophosphates (added or formed in situ) under mild conditions to give the corresponding vicinal halohydrin phosphates in good yields with high re gioselectivity.