Flocculation of model latex particles by chitosans of varying degrees of acetylation

Citation
M. Ashmore et J. Hearn, Flocculation of model latex particles by chitosans of varying degrees of acetylation, LANGMUIR, 16(11), 2000, pp. 4906-4911
Citations number
43
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
16
Issue
11
Year of publication
2000
Pages
4906 - 4911
Database
ISI
SICI code
0743-7463(20000530)16:11<4906:FOMLPB>2.0.ZU;2-Q
Abstract
A series of chitosan samples spanning a wide range of molecular weights hav e been homogeneously acetylated to varying degrees and characterized. These have been used to flocculate a well-characterized "model colloid" polymer latex. The optimum flocculation concentrations have been identified using b oth residual turbidity and initial-rate methods. A charge neutralization me chanism with an enhancement of rate by a "charge patch" effect is shown to operate while both degree of acetylation and molecular weight dan have an e ffect upon the optimum flocculation concentration.