Photoassisted selective catalytic reduction of NO with ammonia in the presence of oxygen at low temperature

Authors
Tanaka, T Teramura, K Funabiki, T
Citation
T. Tanaka et al., Photoassisted selective catalytic reduction of NO with ammonia in the presence of oxygen at low temperature, PHYS CHEM P, 2(12), 2000, pp. 2681-2682
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
12
Year of publication
2000
Pages
2681 - 2682
Database
ISI
SICI code
1463-9076(2000)2:12<2681:PSCRON>2.0.ZU;2-Q
Abstract
Rb-ion-modified V2O5/SiO2 (Rb-VS) was found to be an effective catalyst for photoassisted selective catalytic reduction (SCR) of NO with NH3 in the pr esence of oxygen at room temperature. V2O5/SiO2 and SiO2 did not promote th e reaction either in the dark or with irradiation. The reaction mechanism o ver irradiated Rb-VS is different from the conventional NO SCR with ammonia . NOx is firstly adsorbed over irradiated Rb-VS in the presence of O-2, fol lowed by adsorption of NH3.