M. Lein et al., Electron correlation energies from scaled exchange-correlation kernels: Importance of spatial versus temporal nonlocality, PHYS REV B, 61(20), 2000, pp. 13431-13437
Within density functional theory, a coordinate-scaling relation for the cou
pling-constant dependence of the exchange-correlation kernel f(xc)(r,r';ome
ga) is utilized to express the correlation energy of a many-electron system
in terms of f(xc). As a test of several of the available approximations fo
r the exchange-correlation kernal, or equivalently the local-field factor,
we calculate the uniform-gas correlation energy. While the random phase app
roximation (f(xc) = 0) makes the correlation energy per electron too negati
ve by about: 0.5 eV, the adiabatic local-density approximation [f(xc) = f(x
c)(q = 0,omega =; 0)] makes a comparable error in the opposite direction. T
he adiabatic nonlocal approximation [f(xc) = f(xc)(q, omega = 0)] reduces t
his error to about 0.1 eV, and inclusion of the full frequency dependence [
f(xc) = f(xc)(q,omega)] in an approximate parametrization reduces it furthe
r to less tl;an 0.02 eV. We also report the wave-vector analysis and the im
aginary-frequency analysis of the correlation energy for each choice of ker
nel.