We study the potential effects of anomalous couplings of the third generati
on quarks to gauge bosons in rare B decays. We focus on the constraints fro
m flavor changing neutral current processes such as b-->s gamma and b -->sl
(+)l(-). We consider both dimension-four and dimension-five operators and s
how that the latter can give large deviations from the standard model in th
e still unobserved dilepton modes, even after the bounds from b-->s gamma a
nd precision electroweak observables are taken into account.