Heliotropium crassifolium Boiss, (Boraginaceae) from a population of llam,
western region of Iran was studied for pyrrolizidine alklaoids (PAs). Four
alkaloids have been identified: europine 1, europine N-oxide a and a new py
rrolizidine alkaloids ilamine 3 and its N-oxide 4, respectively. Their stru
ctures were elucidated by IR, H-1-MMR and EIMS data.