The study of chemical reactions, absorption and extraction, using apparatuses with serpentine pipe for pelliclizing-bubbling, xiv. Hydroperoxidation of 1,3-diisopropylbenzene with oxygen

Authors
Vodnar, J Bekassy, S Farkas, J
Citation
J. Vodnar et al., The study of chemical reactions, absorption and extraction, using apparatuses with serpentine pipe for pelliclizing-bubbling, xiv. Hydroperoxidation of 1,3-diisopropylbenzene with oxygen, REACT KIN C, 68(2), 1999, pp. 213-219
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
68
Issue
2
Year of publication
1999
Pages
213 - 219
Database
ISI
SICI code
0133-1736(199911)68:2<213:TSOCRA>2.0.ZU;2-O
Abstract
Experimental results obtained by thermal hydroperoxidation of 1,3-diisoprop ylbenzene in the temperature region of 102-125 degrees C, using a Vodnar-1 type apparatus with discontinuous operation are presented. Based on the res ults, the activation energy (E = 48.5+/-2 kJ/mol), enthalpy (Delta H+ = 47/-2 kJ/mol), entropy (Delta S+) and the activation free enthalpy (Delta G()) were calculated.