Kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutions

Citation
Ay. Gerchikov et al., Kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutions, REACT KIN C, 68(2), 1999, pp. 257-263
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
68
Issue
2
Year of publication
1999
Pages
257 - 263
Database
ISI
SICI code
0133-1736(199911)68:2<257:KOOOAA>2.0.ZU;2-A
Abstract
The kinetics of oxidation of aliphatic alcohols by ozone in aqueous solutio ns was investigated in the temperature interval of 292-317 K. The activatio n parameters of the reaction were determined. The dissociation energies of CH-bonds of the studied substrates were calculated with the use of the AM1 semiempirical method.