Enthalpies of elementary chain propagation steps in the oxidation of organic compounds

Authors
Borisov, IM Mikhaylov, DA Khursan, SL
Citation
Im. Borisov et al., Enthalpies of elementary chain propagation steps in the oxidation of organic compounds, REACT KIN C, 68(2), 1999, pp. 285-289
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
68
Issue
2
Year of publication
1999
Pages
285 - 289
Database
ISI
SICI code
0133-1736(199911)68:2<285:EOECPS>2.0.ZU;2-N
Abstract
A calculation of the enthalpies of elementary steps of the intra- and inter molecular chain propagation for model oxidation reactions of ethers, esters , ketones and hydrocarbons has been carried out. The heats of the intermole cular and intramolecular transfer of flee valence with participation of per oxy radicals and C-H bond of the oxygen-containing compounds are shown to b e comparable.