Thermal decomposition of diazocompounds in aerated solutions. Possible realization of a quantum-chain process

Authors
Nazarov, AM Khursan, SL Yamilova, GA
Citation
Am. Nazarov et al., Thermal decomposition of diazocompounds in aerated solutions. Possible realization of a quantum-chain process, REACT KIN C, 68(2), 1999, pp. 299-305
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
68
Issue
2
Year of publication
1999
Pages
299 - 305
Database
ISI
SICI code
0133-1736(199911)68:2<299:TDODIA>2.0.ZU;2-8
Abstract
Thermal decomposition (85 degrees (N) over tilde;, o-C6H4Cl2, O-2) of RN2 d iazocompounds (R-Ph2C (I), p-Cl-Ph(Ph)C (II), (p-Me2N-Ph)(2)C (III), Me(Ph) C (IV), fluorenylidene Fl (V), adamantylidene Ad (VI)) is accompanied with chemiluminescence (CL) in the visible region of spectrum. The effect of exp erimental conditions on CL intensity was studied, as well as the decomposit ion kinetics of RN2. In (IV) the rate constant of the process was found to depend on the initial concentration of RN2, which is caused by quantum-chai n consumption of the diazocompound.