Frequency of OH in solutions of n-butanol in carbon tetrachloride: effect of dilution

Authors
Srivastava, PK Rai, DK Rai, SB
Citation
Pk. Srivastava et al., Frequency of OH in solutions of n-butanol in carbon tetrachloride: effect of dilution, SPECT ACT A, 56(7), 2000, pp. 1283-1289
Citations number
2
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN journal
13861425 → ACNP
Volume
56
Issue
7
Year of publication
2000
Pages
1283 - 1289
Database
ISI
SICI code
1386-1425(200006)56:7<1283:FOOISO>2.0.ZU;2-E
Abstract
It is noted that the 1<--0 transition for nu(OH) shows a blue shift as the relative concentration of n-butanol in a CCl4-n-butanol is reduced. The mag nitude of the shift decreases for the 2<--0 transition and there is almost no shift for the 3<--0 transition. These observations are consistent with t he observed red shift [Y. Mizugai, F. Takimoto, M. Katayama, Chem. Phys. Le tt. 76 (1980) 615] on dilution for the 5<--0 transition in n-butanol. The o bservations have been interpreted on the basis of formation of O-H....Cl hy drogen bond. (C) 2000 Elsevier Science B.V. All rights reserved.