The relative rate of hydrolysis of a series of acyclic and six-membered cyclic acetals, ketals, orthoesters, and orthocarbonates

Citation
P. Deslongchamps et al., The relative rate of hydrolysis of a series of acyclic and six-membered cyclic acetals, ketals, orthoesters, and orthocarbonates, TETRAHEDRON, 56(22), 2000, pp. 3533-3537
Citations number
35
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
22
Year of publication
2000
Pages
3533 - 3537
Database
ISI
SICI code
0040-4020(20000526)56:22<3533:TRROHO>2.0.ZU;2-L
Abstract
The relative rate of hydrolysis of these compounds is rationalized by consi dering the influence of steric, inductive and stereoelectronic effects on t he hydrolysis reaction mechanism. (C) 2000 Elsevier Science Ltd. All rights reserved.