Silver and lead contacts prepared by evaporation onto clean n-GaN(0001
) surfaces are rectifying. Their zero-bias barrier heights and idealit
y factors were determined from the current-voltage characteristics. Th
e observed linear correlation between the barrier heights and the idea
lity factors is attributed to nonuniform distributions of barrier heig
hts along the interfaces, The barrier heights of ideal Schottky contac
ts depend on the applied voltage due to the image-force lowering only
and their ideally factors n(if) are approximately 1.01. By extrapolati
on of our experimental data to ii = 1.01. we obtain barrier heights of
0.82 eV and 0.73 eV for uniform Ag- and Pb/n-GaN(0001) contacts, resp
ectively. By applying the idea of metal-induced gap states (MIGS), the
barrier heights of ideal Schottky contacts have been predicted to var
y linearly as a function of the difference of the metal and the semico
nductor electronegativities. The zero-charge-transfer barrier height a
nd slope parameter are characteristic of the respective semiconductor.
The zero-charge-transfer barrier heights have been calculated using a
n empirical tight-binding approach and the slope parameters are given
by the optical dielectric constants. The experimental barrier heights
of GaN Schottky contacts confirm the predictions of the MIGS-and-elect
ronegativity model.