Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD

Authors
Ohtsu, H Itoh, S Nagatomo, S Kitagawa, T Ogo, S Watanabe, Y Fukuzumi, S
Citation
H. Ohtsu et al., Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD, CHEM COMMUN, (12), 2000, pp. 1051-1052
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
12
Year of publication
2000
Pages
1051 - 1052
Database
ISI
SICI code
1359-7345(2000):12<1051:COICHA>2.0.ZU;2-Q
Abstract
Imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)- Cu(II) homodi nuclear hydroperoxo complexes are generated in the reactions between imidaz olate-bridged heterodinuclear and homodinuclear complexes and H2O2 in the p resence of triethylamine base and characterized spectroscopically as reacti on intermediate models of Cu,Zn-SOD.