Alkoxylation and hydration of camphene in the presence of acid catalysts

Authors
Radbil', AB Kulikov, MV Sokolova, TN Kartashov, VR Zolin, BA Radbil', BA
Citation
Ab. Radbil' et al., Alkoxylation and hydration of camphene in the presence of acid catalysts, CHEM NAT CO, 35(5), 1999, pp. 524-528
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
CHEMISTRY OF NATURAL COMPOUNDS
ISSN journal
00093130 → ACNP
Volume
35
Issue
5
Year of publication
1999
Pages
524 - 528
Database
ISI
SICI code
0009-3130(199909/10)35:5<524:AAHOCI>2.0.ZU;2-M
Abstract
The alkoxylation of camphene in the presence of various arid catalysts is s tudied. Alkylisobornyl ethers are obtained in high yields if the heteropoly acids H4SiW12O40 and H3PW12O40 are used as the catalysts. The mechanism of the acid-catalysed hydration of camphene in aqueous-alcohol solutions is ex amined.